ELASTOMERS AND PLASTICS Application of Horikx’s Theory for devulcanized Scrap Rubbers

Von Quentin Jean, Yvan Chalamet, Jean Charles Majesté, Christian Carrot, Saint Etienne, Claude Janin, Bernard Cantaloube, Patrick Heuillet, Vitry-sur-Seine, France 0 min Lesedauer

End-of-life of scrap rubber is an important environmental issue. Many studies have tried to develop or to improve recycling methods by means of devulcanization processes, if possible in a continuous way. In this frame, the Horikx’s theory is widely used to characterize devulcanized rubbers especially as a method to assess the degree and the quality of the devulcanization process

Horikx’s diagram plot  for a pristine elastomer. The black line corresponds to pure random chain scission mechanism. The red  line is the limit for pure selective crosslink scission mechanism.(Bild:)
Horikx’s diagram plot for a pristine elastomer. The black line corresponds to pure random chain scission mechanism. The red line is the limit for pure selective crosslink scission mechanism.
(Bild:)

A lot of methods have been developed to regenerate waste rubber including thermomechanical, chemical, ultrasound assisted or microwave assisted processes. All the processes of reclaiming aim at transforming the three-dimensional network in a structure that gives thermoplastic behaviour to the material.